Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 62: Issue 1
Phase Diagram of EC–DMC Binary System and Enthalpic Determination of Its Eutectic Composition
Authors:
M. Ding Army Research Laboratory 2800 Powder Mill Road Adelphi MD 20783 USA 2800 Powder Mill Road Adelphi MD 20783 USA

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K. Xu Army Research Laboratory 2800 Powder Mill Road Adelphi MD 20783 USA 2800 Powder Mill Road Adelphi MD 20783 USA

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, and
T. Jow Army Research Laboratory 2800 Powder Mill Road Adelphi MD 20783 USA 2800 Powder Mill Road Adelphi MD 20783 USA

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Pages:
177–186
Online Publication Date:
02 Nov 2004
Publication Date:
01 Oct 2000
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010175114578
Keywords:
binary phase diagram; DSC; enthalpic method; eutectic composition
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Abstract  

We construct with a differential scanning calorimeter (DSC) a phase diagram for the ethylene carbonate (EC)-dimethyl carbonate (DMC) binary system for its liquid-solid phase equilibria. We determine the eutectic composition of the binary system using an enthalpic method that we devised based on the composition dependence of the enthalpy of solidus melting, with highly consistent results. We also discuss the merits and limitations of this enthalpic method.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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