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  • 1 Nizhny Novgorod State University Chemistry Institute Nizhny Novgorod Russia Nizhny Novgorod Russia
  • 2 Institute of Chemical Physics Problems of RAS, Chernogolovka Moscow Region Russia Moscow Region Russia
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Abstract  

The temperature dependence of the molar heat capacity (C0p) of hydrofullerene C60H36 between 5 and 340 K was determined by adiabatic vacuum calorimetry with an error of about 0.2%. The experimental data were used for the calculation of the thermodynamic functions of the compound in the range 0 to340 K. It was found that at T=298.15 K and p=101.325 kPa C0p (298.15)=690.0 J K−1 mol−1,Ho(298.15)−Ho(0)= 84.94 kJ mol−1,So(298.15)=506.8 J K−1 mol−1, Go(298.15)−Ho(0)= −66.17 kJ mol−1. The standard entropy of formation of hydrofullerene C60H36 and the entropy of reaction of its formation by hydrogenation of fullerene C60 with hydrogen were estimated and at T=298.15 K they were ΔfSo= −2188.4 J K−1 mol−1 and ΔrSo= −2270.5 J K−1mol−1, respectively.