Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 62: Issue 1
Thermodynamic Properties of Hydrofullerene C60H36 from 5 to 340 K
Authors:
B. Lebedev Nizhny Novgorod State University Chemistry Institute Nizhny Novgorod Russia Nizhny Novgorod Russia

Search for other papers by B. Lebedev in
Current site
Google Scholar
PubMed Close
,
T. Bykova Nizhny Novgorod State University Chemistry Institute Nizhny Novgorod Russia Nizhny Novgorod Russia

Search for other papers by T. Bykova in
Current site
Google Scholar
PubMed Close
, and
A. Lobach Institute of Chemical Physics Problems of RAS, Chernogolovka Moscow Region Russia Moscow Region Russia

Search for other papers by A. Lobach in
Current site
Google Scholar
PubMed Close
Pages:
257–265
Online Publication Date:
02 Nov 2004
Publication Date:
01 Oct 2000
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010139501374
Keywords:
adiabatic vacuum calorimeter; heat capacity; hydrofullerene C60H36; thermodynamic functions
Restricted access

Abstract  

The temperature dependence of the molar heat capacity (C0p) of hydrofullerene C60H36 between 5 and 340 K was determined by adiabatic vacuum calorimetry with an error of about 0.2%. The experimental data were used for the calculation of the thermodynamic functions of the compound in the range 0 to340 K. It was found that at T=298.15 K and p=101.325 kPa C0p (298.15)=690.0 J K−1 mol−1,Ho(298.15)−Ho(0)= 84.94 kJ mol−1,So(298.15)=506.8 J K−1 mol−1, Go(298.15)−Ho(0)= −66.17 kJ mol−1. The standard entropy of formation of hydrofullerene C60H36 and the entropy of reaction of its formation by hydrogenation of fullerene C60 with hydrogen were estimated and at T=298.15 K they were ΔfSo= −2188.4 J K−1 mol−1 and ΔrSo= −2270.5 J K−1mol−1, respectively.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Apr 2024 15 0 0
May 2024 0 0 0
Jun 2024 2 0 0
Jul 2024 2 0 0
Aug 2024 12 0 0
Sep 2024 13 0 0
Oct 2024 5 0 0