Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 62: Issue 2
Influence of Encapsulation on The Mechanism of Thermal Destruction of Cyanide Transition Metal Complexes
Authors:
Yu. Goltsov National Academy of Sciences of Ukraine L. V. Pisarzhevsky Institute of Physical Chemistry 31 Prospekt Nauki 03039 Kyiv Ukraine 31 Prospekt Nauki 03039 Kyiv Ukraine

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L. Matkovskaya National Academy of Sciences of Ukraine L. V. Pisarzhevsky Institute of Physical Chemistry 31 Prospekt Nauki 03039 Kyiv Ukraine 31 Prospekt Nauki 03039 Kyiv Ukraine

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V. Il'in National Academy of Sciences of Ukraine L. V. Pisarzhevsky Institute of Physical Chemistry 31 Prospekt Nauki 03039 Kyiv Ukraine 31 Prospekt Nauki 03039 Kyiv Ukraine

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V. Golovaty National Academy of Sciences of Ukraine L. V. Pisarzhevsky Institute of Physical Chemistry 31 Prospekt Nauki 03039 Kyiv Ukraine 31 Prospekt Nauki 03039 Kyiv Ukraine

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Pages:
373–379
Online Publication Date:
16 Aug 2006
Publication Date:
01 Nov 2000
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010153107197
Restricted access

Abstract  

The results of investigation of the influence of encapsulation on the mechanism of thermal decomposition of cyanide transition metal complexes, based on data obtained by methods of differential thermal analysis (inert atmosphere) and thermodesorption (mass-spectral monitoring of gaseous products) are represented. It was established, that encapsulation of cyanide iron(II) and cobalt(III) complexes in faujasite type zeolite results in the hydrolytic mechanism of thermal destruction of complexes, unlike to bulk analogues, which is determined by essential decreasing of the temperature of complex anions encapsulated destruction beginning, up to temperatures while zeolite water molecules are saved; the gaseous products of thermal destruction composition is determined by the peculiarities of localization of cations of different nature in inclusion compounds.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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