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  • 1 National Academy of Sciences of Ukraine Institute of Surface Chemistry Prospekt Nauki 31 252022 Kyiv Ukraine Prospekt Nauki 31 252022 Kyiv Ukraine
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Abstract  

The reaction conditions and component ratios were established for the attachment of 4-(2-pyridylazo)resorcinol (PAR), 1-(2-pyridylazo)-2-naphthol (PAN) and 8-hydroxyquinoline (8-HQ) to the silica surface by means of a single-stage Mannich reaction. The modified sorbents that were synthesized were characterized by an adsorption method, and DRIFT and UV spectroscopies. The concentrations of PAR, PAN and 8-HQ grafted to the silica surface that were attained were 2.810−5, 8.510−5 and 2.710−4 mol g−1, respectively.