Authors:
M. Gojić University of Zagreb Faculty of Metallurgy Aleja n. heroja 3 Sisak Croatia Aleja n. heroja 3 Sisak Croatia

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J. Črnko University of Zagreb Faculty of Metallurgy Aleja n. heroja 3 Sisak Croatia Aleja n. heroja 3 Sisak Croatia

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M. Sućeska Marine Research and Special Technology Laboratory for Thermal Analysis Avenija V. Holjevca 20 10000 Zagreb Croatia Avenija V. Holjevca 20 10000 Zagreb Croatia

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M. Rajić Marine Research and Special Technology Laboratory for Thermal Analysis Avenija V. Holjevca 20 10000 Zagreb Croatia Avenija V. Holjevca 20 10000 Zagreb Croatia

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Abstract  

Heat treatment of pipes was performed under industrial conditions at 580C in a dry protective gas containing a CO2–CO–H2–N2 mixture. A commercial adsorbent (733 kg) used for production ofthe gas removed 52.7 l of water in five h and 22.5 min. During the annealing of pipesoxidation and decarburization were not observed. The results were confirmed bymetallographic analysis. The values of enthalpy of water desorption (36.4–40.5 kJ mol–1) obtained by DSC and TG measurements were close to those of water evaporation(44.1 kJ mol–1). This suggests that the bonds between the water molecules andadsorbents were not of chemical but of physical nature.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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