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  • 1 Hebei Teachers' University Experimental Center Shijiazhuang 050016 China Shijiazhuang 050016 China
  • | 2 Hebei Teachers' University Department of Chemistry Shijiazhuang 050016 China Shijiazhuang 050016 China
  • | 3 Hebei Teachers' University Experimental Center Shijiazhuang 050016 China Shijiazhuang 050016 China
  • | 4 Hebei University of Science and Technology Department of Chemistry and Pharmacy Engineering Shijiazhuang 050018 China Shijiazhuang 050018 China
  • | 5 Hebei Medical University Department of Medical Chemistry Shijiazhuang 050017 China Shijiazhuang 050017 China
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Abstract  

The thermal decomposition of Eu2(BA)6(bipy)2 (BA=C2H5N2, benzoate; bipy=C10H8N2, 2,2'-bipyridine)and its kinetics were studied under the non-isothermal condition by TG-DTG, IR and SEM methods. The kinetic parameters were obtained from analysis of the TG-DTG curves by the Achar method, the Madhusudanan-Krishnan-Ninan (MKN) method, the Ozawa method and the Kissinger method. The most probable mechanism function was suggested by comparing the kinetic parameters. The kinetic equation for the first stage can be expressed as: dα/dt=Aexp(–E/RT)3(1–α)2/3.

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