Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 63: Issue 1
Thermal Analysis of Poly(AN—co—St) and Poly(AN—St—MMA)
Authors:
D. Li Hebei University Department of Chemistry Baoding 071002 People's Republic of China Baoding 071002 People's Republic of China

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J. Gao Hebei University Department of Chemistry Baoding 071002 People's Republic of China Baoding 071002 People's Republic of China

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Q. An Hebei University Department of Chemistry Baoding 071002 People's Republic of China Baoding 071002 People's Republic of China

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G. Liu Hebei University Department of Chemistry Baoding 071002 People's Republic of China Baoding 071002 People's Republic of China

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L. Yang Hebei University Department of Chemistry Baoding 071002 People's Republic of China Baoding 071002 People's Republic of China

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Pages:
69–74
Online Publication Date:
02 Nov 2004
Publication Date:
25 Jan 2001
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010176117782
Keywords:
acrylonitrile; copolymer; methyl methacrylate; styrene; thermostability
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Abstract  

Poly(AN—co—St) (PAS) and poly(AN—St—MMA)(PASM) were synthetized by emulsion polymerisation. The glass transition temperatures (Tg) of the copolymers and the relationship between Tg and the components of the copolymers were investigated by differential scanning calorimetry. The results show that Tg for the AN—St bipolymers has apeak value in the range 115–118°C at a content of 50 mass% St. When methyl methacrylate was added, the Tg of the terpolymer was decreased by about 2–6°C.The thermostability and the activation energy E of degradation were determined by thermogravimetric analysis.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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