Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 63: Issue 3
Phase Diagrams of Perhydrotriphenylene and Aromatic Compounds II. Terthiophene and related thiophene oligomers
Authors:
G. Di Silvestro Universita di Milano Dipartimento di Chimica Organica e Industriale Via Venezian 21 I-20133 Milano Italy Via Venezian 21 I-20133 Milano Italy

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C. Yuan Universita di Milano Dipartimento di Chimica Organica e Industriale Via Venezian 21 I-20133 Milano Italy Via Venezian 21 I-20133 Milano Italy

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W. Porzio Istituto di Chimica delle Macromolecole del CNR Via E. Bassini 15 I-20133 Milano Italy Via E. Bassini 15 I-20133 Milano Italy

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Pages:
663–669
Online Publication Date:
16 Aug 2006
Publication Date:
01 Mar 2001
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010171516684
Keywords:
inclusion compounds; perhydrotriphenylene; phase diagrams; quater-, penta- and α,ω-dihexylquaterthiophene
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Abstract  

Terthiophene included in a perhydrotriphenylene (PHTP) adduct exhibits an UV spectrum different from that observed in the bulk or in solution. The X-ray diffraction pattern also differs significantly from that of pure PHTP. The UV spectrum is interpreted as due to an isolated molecule in a vacuum-like space, in agreement with a model developed from X-ray diffraction data. Knowledge of the phase diagram was essential for an interpretation of the optical properties and of some kinetic aspects of the formation of the inclusion compound phase. In this work, the phase diagrams of terthiophene (T3) are presented, and DSC evidence of the inclusion of quater- (T4), penta- (T5)and α,ω-dihexylquaterthiophene (DH4T) is discussed.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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