Authors:
M. Fujisawa Kinki University Department of Biotechnological Science Uchita-cho, Naga-gun, Wakayama 649-6493 Japan Uchita-cho, Naga-gun, Wakayama 649-6493 Japan

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T. Kimura Kinki University Department of Chemistry Kowakae, Higashi-osaka 577-8502 Japan Kowakae, Higashi-osaka 577-8502 Japan

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S. Takagi Kinki University Department of Chemistry Kowakae, Higashi-osaka 577-8502 Japan Kowakae, Higashi-osaka 577-8502 Japan

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Abstract  

The enthalpies, entropies and Gibbs energies of inclusion of dl-1,3-, 1,4- and meso-2,3-butanediols into α- and β-cyclodextrin cavities from ideal gas phase have been determined on the basis of newly obtained experimental data of the butanediols. The butanediol molecules are stabilised strongly in the cavities due to interactions with inner walls of the cavities. Entropies of the gaseous isomers are greatly decreased in the cavities. The largest decrease is obtained for the case of 2,3-BD. Discussions concerning the1,4-butanediol given in the preceding paper have been changed due to the adoption of new data on the butanediols.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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