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  • 1 Technical University of Szczecin Institute of Chemistry and Environment Protection Al. Piastów 42 71-065 Szczecin Poland Al. Piastów 42 71-065 Szczecin Poland
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Abstract  

Studies on the reaction kinetics and mechanism of the synthesis of the Zn2.5VMoO8 compound in the solid state have been carried out in situ in a high-temperature X-ray diffraction attachment. The apparent activation energy, 21226 kJ mol-1 was calculated by using the diffusion controlled Ginstling-Brounstein model. There was also determined a temperature dependence of unit cell parameters for Zn3V2O8 and Zn2.5VMoO8.