Author: D. Fatu 1
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  • 1 University of Bucharest Department of Physical Chemistry, Faculty of Chemistry Blv. Elisabeta 4–12 Bucharest 70346 Romania Blv. Elisabeta 4–12 Bucharest 70346 Romania
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Abstract  

The object of this work is the quantitative explanation of linear correlation between activation energy (E), initial decomposition temperature (Ti) and ionic potential (Vi), observed for thermal degradation of some complexes of transitional metals. The proposed model allowed the evaluation of characteristic parameter proportional to the activation free enthalpy and also the variation of effective electrical charge (ΔQ*) of ligand, in the formation process of the activated complex. These results are satisfactory, taking into account that we utilized many simple hypotheses for deduction of Arrhenius equation.

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