Author: D. Fatu 1
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  • 1 University of Bucharest Department of Physical Chemistry, Faculty of Chemistry Blv. Elisabeta 4–12 Bucharest 70346 Romania Blv. Elisabeta 4–12 Bucharest 70346 Romania
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Abstract  

The object of this work is the quantitative explanation of linear correlation between activation energy (E), initial decomposition temperature (Ti) and ionic potential (Vi), observed for thermal degradation of some complexes of transitional metals. The proposed model allowed the evaluation of characteristic parameter proportional to the activation free enthalpy and also the variation of effective electrical charge (ΔQ*) of ligand, in the formation process of the activated complex. These results are satisfactory, taking into account that we utilized many simple hypotheses for deduction of Arrhenius equation.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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