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  • 1 Universidade de Uberaba Instituto de Ciências Biológicas e da Saúde 38020-100 Uberaba-MG Brazil 38020-100 Uberaba-MG Brazil
  • | 2 Faculdade Ubaense Ozanam Coelho 36500-000 Ubá-MG Brazil 36500-000 Ubá-MG Brazil
  • | 3 Universidade Vale do Rio Verde Instituto Superior de Educação 37410-000 Três Corações-MG Brazil 37410-000 Três Corações-MG Brazil
  • | 4 Universidade Federal de Lavras Departamento de Química 37200-000 Lavras-MG Brazil 37200-000 Lavras-MG Brazil
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The compounds [(LR2Sn)2O] {R=CH3 (Me), n-C4H9(Bn); L=C6H5CH(OH)COO}were studied by thermogravimetric and differential scanning calorimetry in a dynamic atmosphere of helium. The thermal decomposition mechanisms are similar for both compounds and occur in two consecutive steps. The TG curves of the complexes suggest the liberation of the ligand L in the first step, with probable formation of a tin oxide R2SnO intermediate. At the end of the second step free tin is obtained in accordance with the stoichiometry of the related compounds. An inverse relation betweenΔHfusion and solubility of the compounds suggests a polymeric structure for the compound with Bn ligand in relation to the compound with M ligand.

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  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
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  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
per Year
per Year
Founder Akadémiai Kiadó
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)