Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 68: Issue 3
Solid Phase Synthesis, Characterization of Hexamethylenetetramine Complexes of Antimony and Bismuth Trichloride
Authors:
Y. Guo Nanyang Teacher’s College Department of Chemistry Henan, Nanyang 473061 P. R. China Henan, Nanyang 473061 P. R. China

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S. Luan East China University of Science and Technology Department of Chemistry Shanghai 200237 P. R. China Shanghai 200237 P. R. China

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Y. Chen East China University of Science and Technology Department of Chemistry Shanghai 200237 P. R. China Shanghai 200237 P. R. China

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X. Zang East China University of Science and Technology Department of Chemistry Shanghai 200237 P. R. China Shanghai 200237 P. R. China

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Y. Jia East China University of Science and Technology Department of Chemistry Shanghai 200237 P. R. China Shanghai 200237 P. R. China

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G. Zhong Sichuan Institute of Animal Husbandry and Veterinary Medicine Chongqing 402460 P. R. China Chongqing 402460 P. R. China

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S. Ruan Peking University Department of Chemistry Beijing 100871 P. R. China Beijing 100871 P. R. China

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Pages:
1025–1033
Online Publication Date:
01 Nov 2004
Publication Date:
01 Jun 2002
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1016163111068
Keywords:
crystal structure; far-infrared spectra; hexamethylenetetramine complex of Sb and Bi; solid phase synthesis; thermal decomposition
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Abstract  

New hexamethylenetetramine complexes of antimony and bismuth trichloride were synthesized through a solid phase reaction of hexamethylenetetramine and antimony or bismuth trichloride. The formula of the complex is MCl3(C6H12N4)2⋅H2O (M=Sb, Bi).The crystal structure of the complexes belongs to monoclinic system and the lattice parameters: a=1.249 nm, b=1.4583 nm, c=1.6780 nm andβ=91.78 for SbCl3(C6H12N4)2⋅H2O and a=1.3250 nm, b=1.3889 nm, c=1.7449 nm and β=98.94 for BiCl3(C6H12N4)2⋅H2O. Far-infrared spectra reveal that the antimony or bismuth ion is coordinated by the nitrogen atom of the hexamethylenetetramine. The thermal analysis also demonstrates the complex formation between the antimony or bismuth ion and hexamethylenetetramine. The intermediate and final residues in the thermal decomposition process have been analyzed to check the pyrolysis reaction.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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