Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 68: Issue 3
Low temperature heat capacity and thermodynamic functions of LiCoO2
Authors:
H. Kawaji Tokyo Institute of Technology Materials and Structures Laboratory 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8503 Japan 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8503 Japan

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M. Takematsu Tokyo Institute of Technology Materials and Structures Laboratory 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8503 Japan 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8503 Japan

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T. Tojo Tokyo Institute of Technology Materials and Structures Laboratory 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8503 Japan 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8503 Japan

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T. Atake Tokyo Institute of Technology Materials and Structures Laboratory 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8503 Japan 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8503 Japan

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A. Hirano Mie University Department of Chemistry for Materials, Faculty of Engineering Tsu 514-8507 Japan Tsu 514-8507 Japan

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R. Kanno Tokyo Institute of Technology Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8502 Japan 4259 Nagatsuta-cho Midori-ku, Yokohama 226-8502 Japan

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Pages:
833–839
Online Publication Date:
01 Nov 2004
Publication Date:
01 Jun 2002
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1016169917912
Keywords:
heat capacity; LiCoO2; thermodynamic functions
Restricted access

Abstract  

The sample of LiCoO2 was synthesized, and the heat capacity was measured by adiabatic calorimetry between 13 and 300 K. The smoothed values of the heat capacity were calculated from the data. The thermodynamic functions, standard enthalpy, entropy and Gibbs energy, of LiCoO2 were calculated from the heat capacity and the numerical values are tabulated at selected temperatures from 15 to 300 K. The heat capacity, enthalpy, entropy, and Gibbs energy at T=298.15 K are 71.57 J K–1mol–1, 9.853 kJ mol–1, 52.45 J K–1 mol–1, –5.786 kJ mol–1, respectively.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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