Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 69: Issue 2
Studies on the thermal decomposition of N,N'-ethylenebis(salicylideneiminato) diaquochromium(III) nitrate
Authors:
H.-D. Wang

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Y.-T. Li Sichuan University Faculty of Chemistry Chengdu 610064 P. R. China Chengdu 610064 P. R. China

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P.-H. Ma The Chinese Academy of Sciences Qinghai Institute of Salt Lakes Xining 810008 P. R. China Xining 810008 P. R. China

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X.-C. Zeng Sichuan University Faculty of Chemistry Chengdu 610064 P. R. China Chengdu 610064 P. R. China

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Pages:
575–581
Online Publication Date:
02 Nov 2004
Publication Date:
25 Aug 2002
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1019968024792
Keywords:
thermal decomposition; non-isothermal kinetic; X-ray analysis; Cr(III) complex; IR spectrum
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Abstract  

A complex of N,N'-ethylenebis(salicylideneiminato)diaquochromium(III) nitrate, [Cr(salen)(H2O)2]NO3 was characterized and its decomposition mechanism was studied by TG. The IR spectrum and X-ray analysis were examined for the complex. The non-isothermal kinetic data were analyzed by means of the Achar method and the Coats—Redfern method. The most probable kinetic model function was suggested by comparison of the kinetic parameters.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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