Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 69: Issue 3
Binary mixtures of cyclohexanone, 2-butanone, 1,4-dioxane and 1,2-dimethoxyethane
Authors:
K. Tamura Osaka City University Department of Chemistry, Graduate School of Science 3-3-138, Sugimoto Sumiyoshi-ku, Osaka 558-8585 Japan

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and
T. Yamasawa Osaka City University Department of Chemistry, Graduate School of Science 3-3-138, Sugimoto Sumiyoshi-ku, Osaka 558-8585 Japan

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Pages:
849–863
Online Publication Date:
02 Nov 2004
Publication Date:
01 Jul 2002
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1020655906079
Keywords:
excess isentropic and isothermal compressibilities; excess volume and thermal expansion factor; binary mixtures; excess isochoric heat capacity
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Abstract  

Densities and sound velocities of binary mixtures of cyclohexanone, 2-butanone, 1,4-dioxane and 1,2-dimethoxyethane were measured at 298.15 K and also the densities at 303.15 K. Excess volumes were determined from densities. Isentropic compressibilities were determined from densities and sound velocities, and excess thermal expansion factors were determined from excess volumes of two temperatures. Excess isothermal compressibilities and excess isochoric heat capacities were then estimated using excess isobaric heat capacities previously reported. Excess volumes and excess isentropic and isothermal compressibilities were negative except for cyclohexanone+1,4-dioxane system.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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