Authors:
M. MuraiGakushuin University Department of Chemistry 1-5-1 Mejiro Toshima-ku, Tokyo 171-8588 Japan 1-5-1 Mejiro Toshima-ku, Tokyo 171-8588 Japan

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H. NakayamaGakushuin University Department of Chemistry 1-5-1 Mejiro Toshima-ku, Tokyo 171-8588 Japan 1-5-1 Mejiro Toshima-ku, Tokyo 171-8588 Japan

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K. IshiiGakushuin University Department of Chemistry 1-5-1 Mejiro Toshima-ku, Tokyo 171-8588 Japan 1-5-1 Mejiro Toshima-ku, Tokyo 171-8588 Japan

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Abstract  

Crystallization and glass-transition phenomena were studied for amorphous chlorobenzene (CB)/toluene (TL) binary systems as the function of composition. Samples were prepared by vapor-deposition onto cold substrates, and their structural changes due to temperature elevation were monitored with Raman scattering and light transmission. It was found that the crystallization temperature (Tc) of CB-rich amorphous samples increases as the TL concentration is increased. This is similar to the linear dependence of glass-transition temperatures (Tg) of many organic compounds on the concentration of additive. Also found was that Tc of TL-rich supercooled-liquids decrease as the CB concentration is increased. Issues related to the two kinds of Tc are discussed briefly.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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Author:
J. Davidovits