Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 71: Issue 2
Thermal properties of rhodium(III) chloride
Author:
W. Balcerowiak Institute of Heavy Organic Synthesis 47-225 9 Energetyków Str. Kędzierzyn-Koźle Poland 47-225 9 Energetyków Str. Kędzierzyn-Koźle Poland

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Pages:
559–565
Online Publication Date:
31 Oct 2004
Publication Date:
01 Feb 2003
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1022812128136
Keywords:
rhodium(III) chloride; rhodium content determination; TG-DTA; DSC; TG
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Abstract  

Thermal decomposition of rhodium(III) chloride under inert, oxidative and reductive gas atmospheres was investigated in order to determine its thermal properties. Stoichiometries of the reactions occurring during heating are described. it is suggested that the chemical formula of soluble rhodium(III) chloride should be presented as RhCl3HCLxH2O. Cold crystallisation of anhydrous rhodium(III) chloride at a temperature of about 500C was established. The procedure for quantitative determination of volatile matter (water and hydrochloric acid) content and rhodium content by thermogravimetry is given and discussed. The repeatability and reproducibility of the method are estimated.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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