Authors:
D. Silva Universidade Estadual Paulista Instituto de Química P.O. Box 355 14801-900 Araraquara-SP Brasil P.O. Box 355 14801-900 Araraquara-SP Brasil

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C. Ribeiro Universidade Estadual Paulista Instituto de Química P.O. Box 355 14801-900 Araraquara-SP Brasil P.O. Box 355 14801-900 Araraquara-SP Brasil

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M. Crespi Universidade Estadual Paulista Instituto de Química P.O. Box 355 14801-900 Araraquara-SP Brasil P.O. Box 355 14801-900 Araraquara-SP Brasil

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Abstract  

Fluoride glasses have been extensively studied due to their high transparency in the infrared wavelength. The crystallization kinetics of these systems has been studied using DTA and DSC techniques. Most of the experimental data is frequently investigated in terms of the Johnson-Mehl-Avrami (JMA) model in order to obtain kinetic parameters. In this work, DSC technique has been used to study the crystallization of fluorozirconate glass under non-isothermal conditions. It was found that JMA model was not fit to be applied directly to these systems, therefore, the method proposed by Mlek has been applied and the Šestk-Berggren (SB) model seems to be adequate to describe the crystallization process.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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