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  • 1 Kurnakov Institute of General and Inorganic Chemistry Leninsky pr.31 Moscow 119991 Russia Leninsky pr.31 Moscow 119991 Russia
  • | 2 Federal Unitary State Enterprise 'Siberian Group of Chemical Enterprises' (SGChE) Kurchatov str.1 Seversk, Tomsk Region 636000 Russia Kurchatov str.1 Seversk, Tomsk Region 636000 Russia
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Abstract  

Enthalpy of formation of lithium hexafluorophosphate was calculated based on the differential scanning calorimetry study of heat capacity and thermal decomposition. It was found that thermal decomposition of LiPF6 proceeds at normal pressure in the temperature range 450-550 K. Enthalpy of LiPF6 decomposition is ΔdH(LiPF6, c, 298.15 K)= 84.271.34 kJ mole-1. Enthalpy of formation of lithium hexafluorophosphate from elements in standard state is ΔfH0(LiPF6,c, 298.15 K) = -22963 kJ mol-1.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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