Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 73: Issue 3
Thermochemistry of the complexes of some microelements and histidine
Authors:
S. Chen Northwest University Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry Xi'an 710069 P.R. China Xi'an 710069 P.R. China

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Sh Gao Northwest University Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry Xi'an 710069 P.R. China Xi'an 710069 P.R. China

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X. Yang Northwest University Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry Xi'an 710069 P.R. China Xi'an 710069 P.R. China

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R. Hu Northwest University Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry Xi'an 710069 P.R. China Xi'an 710069 P.R. China

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Q. Shi Northwest University Institute of Modern Applied Chemistry 330047 Nanchang Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry Xi'an 710069 P.R. China Xi'an 710069 P.R. China

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Pages:
967–975
Online Publication Date:
31 Oct 2004
Publication Date:
01 Sep 2003
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1025871606585
Keywords:
histidine; transition metal ion; characterization; standard enthalpy of formation; solid complex
Restricted access

Abstract  

Solid complexes of M(His)2Cl2nH2O (M=Mn, Co, Ni, Cu) of MnCl26H2O, CoCl26H2O, NiCl26H2O, CuCl22H2O and L-α-histidine (His) have been prepared in 95% ethanol solution and characterized by elemental analyses, chemical analyses, IR and TG-DTG. The constant-volume combustion energies of the complexes have been determined by a rotating-bomb calorimeter. And the standard enthalpies of formation of the complexes have been calculated as well.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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