Authors:
P. Melnikov CCET/UFMS Physics Department Caixa Postal 549 Campo Grande/MS Brazil Caixa Postal 549 Campo Grande/MS Brazil

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R. Rolim CCET/UFMS Physics Department Caixa Postal 549 Campo Grande/MS Brazil Caixa Postal 549 Campo Grande/MS Brazil

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A. Delben CCET/UFMS Physics Department Caixa Postal 549 Campo Grande/MS Brazil Caixa Postal 549 Campo Grande/MS Brazil

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J. Delben CCET/UFMS Physics Department Caixa Postal 549 Campo Grande/MS Brazil Caixa Postal 549 Campo Grande/MS Brazil

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A. Souza CCET/UFMS Physics Department Caixa Postal 549 Campo Grande/MS Brazil Caixa Postal 549 Campo Grande/MS Brazil

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A. Job UNESP Faculty of Science and Technology Rua Roberto Simonsen 305 Presidente Prudente/SP Brazil Rua Roberto Simonsen 305 Presidente Prudente/SP Brazil

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Abstract  

Xerogels were prepared from zirconium, barium, aluminum, lanthanum and lithium acetates, corresponding to a Li containing ZBLA composition. The study of their thermal properties (DSC, TG/DTG, FT-IR) showed that they might be used as chemically stable precursors in the preparation of fluoride glasses. Hydrofluoric acid in solution was chosen as a mild fluorinating agent. This newly proposed technique of fluorinating allowed to obtain high quality ZBLALi glass which presents the advantage of higher thermal stability and homogeneity in comparison with the glass obtained using individual commercial fluorides.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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