Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 75: Issue 2
Thermochemical parameters of dimethyl and di-iso-propyl dithiocarbamate complexes of palladium(II)
Authors:
J. Regis Botelho Universidade Federal da Paraíba LTM, Departamento de Química, CCEN 58059-900 Joăo Pessoa Paraíba Brazil E-mail 58059-900 Joăo Pessoa Paraíba Brazil E-mail

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A. Duarte Gondim Universidade Federal da Paraíba LTM, Departamento de Química, CCEN 58059-900 Joăo Pessoa Paraíba Brazil E-mail 58059-900 Joăo Pessoa Paraíba Brazil E-mail

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I. Garcia dos Santos Universidade Federal da Paraíba LTM, Departamento de Química, CCEN 58059-900 Joăo Pessoa Paraíba Brazil E-mail 58059-900 Joăo Pessoa Paraíba Brazil E-mail

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P. Dunstan Universidade Estadual de Campinas Instituto de Química 13083-970 Campinas Săo Paulo Brazil 13083-970 Campinas Săo Paulo Brazil

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A. Souza Universidade Federal da Paraíba LTM, Departamento de Química, CCEN 58059-900 Joăo Pessoa Paraíba Brazil E-mail 58059-900 Joăo Pessoa Paraíba Brazil E-mail

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V. Fernandes Universidade Federal do Rio Grande do Norte Departamento de Química, CCET Natal RN Brazil Natal RN Brazil

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A. Araújo Universidade Federal do Rio Grande do Norte Departamento de Química, CCET Natal RN Brazil Natal RN Brazil

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Pages:
607–613
Online Publication Date:
02 Nov 2004
Publication Date:
01 Feb 2004
Article Category:
Research Article
DOI:
https://doi.org/10.1023/b:jtan.0000027152.50431.39
Keywords:
enthalpy; palladium; calorimetry; dialkyl dithiocarbamate
Restricted access

Abstract  

The standard molar enthalpy of formation of crystalline dialkyldithiocarbamate chelates, [Pd(S2CNR2)2], with R=CH3 and i-C3H7, was determined through reaction-solution calorimetry in 1,2-dichloroethane, at 298 K. Using the standard molar enthalpies of formation of the gaseous chelates, the homolytic (52618 and 66610) and heterolytic (269318 and 295710 kJ mol-1) mean enthalpies of palladium-sulphur bond dissociation were calculated.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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