Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 76: Issue 1
Synthesis and thermal decomposition of lanthanide hexacyanochromate(iii) complexes, Ln[Cr(CN)6]·nH2O (Ln=La-Lu; n=3, 4)
Authors:
R. Jia East China University of Science and Technology Department of Chemistry Shanghai 200237 P. R. China Shanghai 200237 P. R. China

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Y, Yang East China University of Science and Technology Department of Chemistry Shanghai 200237 P. R. China Shanghai 200237 P. R. China

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Y. Chen East China University of Science and Technology Department of Chemistry Shanghai 200237 P. R. China Shanghai 200237 P. R. China

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Y.Q. Jia East China University of Science and Technology Department of Chemistry Shanghai 200237 P. R. China Shanghai 200237 P. R. China

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Pages:
157–163
Online Publication Date:
03 Nov 2004
Publication Date:
01 Apr 2004
Article Category:
Research Article
DOI:
https://doi.org/10.1023/b:jtan.0000027815.73030.29
Keywords:
solid phase synthesis; thermal decomposition; crystal structure; nitrilotriacetic acid complex of bismuth
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Abstract  

New solid complex of nitrilotriacetic acid and bismuth trichloride was synthesized by a solid phase reaction of nitrilotriacetic acid and bismuth trichloride at room temperature. The composition of the sample is BiCl3[N(CH2COOH)3]2.5. The crystal structure of the complex belongs to triclinic system with the lattice parameters: α=0.7849 nm, β=0.9821 nm, χ=2.0021 nm, α=96.50, β=98.76 and γ=90.49. The far-infrared spectra show the bonding between the Bi ion and N atom of nitrilotriacetic acid. The thermal analysis also demonstrates the complex formation between the bismuth ion and nitrilotriacetic acid. The gaseous pyrolysis product and the final residue in the thermal decomposition process are determined to check the thermal decomposition reaction.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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