View More View Less
  • 1 Dalian Institute of Chemical Physics, Chinese Academy of Sciences Material Thermochemistry Laboratory Dalian 116023 P.R. China Dalian 116023 P.R. China
  • | 2 Hunan Institute of Drug Detection Changsha 410001 P.R. China Changsha 410001 P.R. China
Restricted access

Abstract  

Molar heat capacities (Cp,m) of aspirin were precisely measured with a small sample precision automated adiabatic calorimeter over the temperature range from 78 to 383 K. No phase transition was observed in this temperature region. The polynomial function of Cp,mvs. T was established in the light of the low-temperature heat capacity measurements and least square fitting method. The corresponding function is as follows: for 78 K≤T≤383 K, Cp,m/J mol-1 K-1=19.086X4+15.951X3-5.2548X2+90.192X+176.65, [X=(T-230.50/152.5)]. The thermodynamic functions on the base of the reference temperature of 298.15 K, {ΔHTH298.15} and {ST-S298.15}, were derived. Combustion energy of aspirin (ΔcUm) was determined by static bomb combustion calorimeter. Enthalpy of combustion (ΔcHom) and enthalpy of formation (ΔfHom) were derived through ΔcUm as - (3945.262.63) kJ mol-1 and - (736.411.30) kJ mol-1, respectively.

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

For subscription options, please visit the website of Springer.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
May 2021 27 0 0
Jun 2021 17 0 0
Jul 2021 5 0 0
Aug 2021 3 0 0
Sep 2021 7 0 0
Oct 2021 12 0 0
Nov 2021 0 0 0