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  • 1 Budapest University of Technology and Economics Institute of General and Analytical Chemistry Szt. Gellért tér 4, H-1521 Budapest Hungary
  • | 2 Tallinn University of Technology Department of Materials Science EE-19086 Tallinn Estonia
  • | 3 Helsinki University of Technology Department of Chemical Technology P.O.Box Laboratory of Inorganic and Analytical Chemistry 6100 FIN-02015 Espoo Finland
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Identification and monitoring of gaseous species released during thermal decomposition of the title compound 1, Zn(tu)2Cl2, (tu=thiourea, (NH2)2C=S) have been carried out in flowing air atmosphere up to 800°C by both online coupled TG-EGA-FTIR and simultaneous TG/DTA-EGA-MS. The first gaseous products of 1, between 200 and 240°C, are carbon disulfide (CS2) and ammonia (NH3). At 240°C, an exothermic oxidation of CS2 vapors occurs resulting in a sudden release of sulphur dioxide (SO2) and carbonyl sulphide (COS). An intense evolution of hydrogen cyanide (HCN) and beginning of the evolution of cyanamide (H2NCN) and isothiocyanic acid (HNCS) are also observed just above 240°C. Probably because of condensation and/or polymerization of cyanamide vapors on the windows and mirrors of the FTIR gas cell optics, some strange baseline shape changes are also occurring above 330°C. Above 500°C the oxidation process of organic residues appears to accelerate which is indicated by the increasing concentration of CO2, while above 600°C zinc sulfide starts to oxidize resulting in the evolution of SO2. All species identified by FTIR gas cell were also confirmed by mass spectrometry, except for HNCS.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
per Year
per Year
Founder Akadémiai Kiadó
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)