Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 80: Issue 1
A DSC study of the effect of lead pigments on the drying of cold pressed linseed oil
Authors:
R. E. White Microstructural Analysis Unit, University of Technology Sydney PO Box 123, Broadway, NSW 2007, Australia

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P. S. Thomas Department of Chemistry, Materials and Forensic Sciences, University of Technology Sydney PO Box 123, Broadway, NSW 2007, Australia

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M. R. Phillips Microstructural Analysis Unit, University of Technology Sydney PO Box 123, Broadway, NSW 2007, Australia

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R. Wuhrer Microstructural Analysis Unit, University of Technology Sydney PO Box 123, Broadway, NSW 2007, Australia

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Pages:
237–239
Online Publication Date:
20 May 2005
Publication Date:
01 Mar 2005
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-005-0642-5
Keywords:
DSC; drying oil; lead white; linseed oil; red lead
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Summary Cold pressed linseed oil and paints prepared using the inorganic pigments; lead white and red lead, were characterized using non-isothermal differential scanning calorimetry (DSC) in an air atmosphere to determine the effect of the pigment on the oxidative polymerisation of the drying oil medium. For each paint sample, the onset temperature for oxidation was reduced from 166°C to the range 50 to 60°C when a heating rate of 5 K min-1 was used. In order to determine the rate of drying, the non-isothermal experiments were carried out using a range of heating rates. A change in the mechanism oxidative polymerization was observed as the heating rate was increased.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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