Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 80: Issue 1
{\rtf1\ansi\ansicpg1250\deff0\deflang1038\deflangfe1038\deftab708{\fonttbl{\f0\froman\fprq2\fcharset238{\*\fname Times New Roman;}Times New Roman CE;}} \viewkind4\uc1\pard\f0\fs20 A pseudo-isothermal kinetic analysis of the recrystallisation of nicke
Authors:
P. Thomas Department of Chemistry, Materials and Forensic Sciences, University of Technology Sydney, PO Box 123, Broadway, NSW 2007, Australia

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P. Šimon Department of Physical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology Radlinského 9, 812 37 Bratislava, Slovak Republic

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Pages:
77–80
Online Publication Date:
20 May 2005
Publication Date:
01 Mar 2005
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-005-0616-7
Keywords:
kinetics; DSC; nickel sulphide; recrystallisation
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Summary A pseudo-isothermal method for the kinetic analysis was applied to the recrystallisation of a to ß nickel sulphide based on the Ozawa model for non-isothermal crystallisation in the presence of pre-existing nuclei. The aim of the analysis was to determine the number of steps involved in the recrystallisation and, hence, determine the applicability of the kinetic equation based on a single step mechanism, as is commonly applied in the kinetic analysis of solid-state processes using thermal methods. The kinetic analysis yielded evidence of at least two processes indicating that physical and mechanistic significance should not be drawn from the use of a single step approximation of the rate equation.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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