Authors:
M. M. Mato Departamento de Física Aplicada, Facultad de Ciencias, Universidad de Vigo 36200 Vigo, Spain

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S. M. Cebreiro Departamento de Física Aplicada, Facultad de Físicas, Campus Sur, Universidad de Santiago de Compostela 15782 Santiago de Compostela, Spain

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P. V. Verdes Departamento de Física Aplicada, Facultad de Físicas, Campus Sur, Universidad de Santiago de Compostela 15782 Santiago de Compostela, Spain

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J. L. Legido Departamento de Física Aplicada, Facultad de Ciencias, Universidad de Vigo 36200 Vigo, Spain

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M. I. Paz Andrade Departamento de Física Aplicada, Facultad de Físicas, Campus Sur, Universidad de Santiago de Compostela 15782 Santiago de Compostela, Spain

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Summary Experimental excess molar enthalpies and densities have been measured for the ternary mixture x1MTBE+x21-propanol+(1-x1-x2)octane and the involved binary mixtures at 298.15 K and atmospheric pressure. In addition, excess molar volumes were determined from the densities of the pure liquids and mixtures. A standard Calvet microcalorimeter was employed to determine the excess molar enthalpies. Densities were measured using a DMA 4500 Anton Paar densimeter. The UNIFAC group contribution model (in the versions of Larsen et al., and Gmehling et al.) has been used to estimate excess enthalpies values. Experimental data were also used to test several empirical expressions for estimating ternary properties from experimental binary results.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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