Authors:
M. Domínguez-Pérez Dto. de Física. Fac. de Ciencias. Univ. da Coruña 15072 A Coruña Spain

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J. Jiménez de Llano Dto. de Física. Fac. de Ciencias. Univ. da Coruña 15072 A Coruña Spain

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L. Segade Dto. de Física. Fac. de Ciencias. Univ. da Coruña 15072 A Coruña Spain

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C. Franjo Dto. de Física. Fac. de Ciencias. Univ. da Coruña 15072 A Coruña Spain

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O. Cabeza Dto. de Física. Fac. de Ciencias. Univ. da Coruña 15072 A Coruña Spain

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Summary This paper reports excess molar enthalpies of the binary systems hexane+ethyl benzene, hexane+o-xylene, hexane+m-xylene and hexane+p-xylene at 298.15 K and atmospheric pressure, over the whole composition range. The data was measured directly using a Calvet microcalorimeter. The excess magnitude was correlated to a Redlich-Kister type equation for each mixture. Also, we will discuss the results for the four mixtures studied here and by comparison with the same binary systems but containing propyl propanoate as first component. Finally, we will correlate our results with the Nitta-Chao and the three UNIFAC theoretical approximations.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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