Authors:
M. M. Mato Departamento de Física Aplicada, Facultad de Ciencias, Universidade de Vigo 36200 Vigo, Spain

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S. M. Cebreiro Departamento de Física Aplicada, Facultad de Físicas, Campus Sur, Universidade de Santiago de Compostela 15782 Santiago de Compostela, Spain

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P. V. Verdes Departamento de Física Aplicada, Facultad de Físicas, Campus Sur, Universidade de Santiago de Compostela 15782 Santiago de Compostela, Spain

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J. L. Legido Departamento de Física Aplicada, Facultad de Ciencias, Universidade de Vigo 36200 Vigo, Spain

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M. I. Paz Andrade Departamento de Física Aplicada, Facultad de Físicas, Campus Sur, Universidade de Santiago de Compostela 15782 Santiago de Compostela, Spain

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Summary Experimental excess molar enthalpies and excess molar volumes of the ternary system x1MTBE+x21-propanol+(1-x1-x2) hexane and the involved binary mixtures have been determined at 298.15 K and atmospheric pressure. Excess molar enthalpies were measured using a standard Calvet microcalorimeter, and excess molar volumes were determined from the densities of the pure liquids and mixtures, using a DMA 4500 Anton Paar densimeter. The UNIFAC group contribution model (in the versions of Larsen et al., and Gmehling et al.) has been employed to estimate excess enthalpies values. Several empirical expressions for estimating ternary properties from experimental binary results were applied.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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