Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 80: Issue 3
Thermodynamic data of the NZP compounds family
Authors:
V. I. Pet’kov Department of Chemistry, Nizhni Novgorod State University pr. Gagarina 23, Nizhni Novgorod 603950, Russia

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E. A. Asabina Department of Chemistry, Nizhni Novgorod State University pr. Gagarina 23, Nizhni Novgorod 603950, Russia

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A. V. Markin Department of Chemistry, Nizhni Novgorod State University pr. Gagarina 23, Nizhni Novgorod 603950, Russia

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N. N. Smirnova Department of Chemistry, Nizhni Novgorod State University pr. Gagarina 23, Nizhni Novgorod 603950, Russia

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D. B. Kitaev Department of Chemistry, Nizhni Novgorod State University pr. Gagarina 23, Nizhni Novgorod 603950, Russia

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Pages:
695–700
Online Publication Date:
31 May 2005
Publication Date:
01 Jun 2005
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-005-0716-4
Keywords:
calorimetry; heat capacity; thermodynamic functions; enthalpy of solution; phosphates
Restricted access

Summary The thermodynamic data for NZP compounds MZr2(PO4)3 (M=Na, K, Rb, Cs, Zr0.25) and Na5D(PO4)3 (D=Ti, Zr) are reported. The heat capacities of the phosphates were measured between T=7 and T=640 K. The standard enthalpies entropies, and Gibbs functions of formation at T=298.15 K were derived. The obtained thermodynamic characteristics of phosphates of the NZP type structure and literature data are summarized. Thermodynamic functions of reactions of solid-state synthesis were calculated and the usability of ceramic technology for obtaining NZP compounds was proved.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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