Authors:
S. Y. Jung Department of Applied Chemistry, Graduate School of Engineering, Tokyo Metropolitan University 1-1 Minami-Osawa, Hachiouji, Tokyo 192-0397 Japan

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T. Yamada Department of Applied Chemistry, Graduate School of Engineering, Tokyo Metropolitan University 1-1 Minami-Osawa, Hachiouji, Tokyo 192-0397 Japan

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H. Yoshida Department of Applied Chemistry, Graduate School of Engineering, Tokyo Metropolitan University 1-1 Minami-Osawa, Hachiouji, Tokyo 192-0397 Japan

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T. Iyoda CREST-JST 4-1-8 Honmachi, Kawaguchi, Saitama 332-0012, Japan

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Summary The mixing state of amphiphilic di-block copolymers consisted of poly(ethylene oxide) and poly(methacrylate) having azobenzene moieties in the side chains p(EO)114pMA(Az)24 and poly(ethylene oxide) p(EO)114 was investigated from the viewpoints of isothermal crystallization and nano-scale ordered structure. The chemical potential, which required establishing the constant crystal growth rate, decreased with the p(EO) content up to 60%. The hexagonal packed cylinder structure was observed for the blends with the p(EO) content up to 60% and the lattice spacing of (100) and (110) planes increased with the p(EO) content up to 60%. The blends of amphiphilic p(EO)114pMA(Az)24 and p(EO)114 were miscible without in the p(EO) content below 60%.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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