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  • 1 University of Alabama at Birmingham Department of Chemistry Birmingham USA 35294 AL 901S 14th Str. Birmingham USA 35294 AL 901S 14th Str.
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Abstract  

The paper presents the model-free kinetic approach in the context of the traditional kinetic description based on the kinetic triplet, A, E, and f(α) or g(α). A physical meaning and interpretability of the triplet are considered. It is argued that the experimental values of f(α) or g(α) and A are unlikely to be interpretable in the respective terms of the reaction mechanism and of the vibrational frequency of the activated complex. The traditional kinetic description needs these values for making kinetic predictions. Interpretations are most readily accomplished for the experimental value of E that generally is a function of the activation energies of the individual steps of a condensed phase process. Model-free kinetic analysis produces a dependence of E on α that is sufficient for accomplishing theoretical interpretations and kinetic predictions. Although model-free description does not need the values of A and f(α) or g(α), the methods of their estimating are discussed.

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)