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  • 1 National Yunlin University of Science and Technology, NYUST Doctoral Program of Engineering Science and Technology Douliou, Yunlin Taiwan, ROC 64002 123, University Rd., Sec. 3 Douliou, Yunlin Taiwan, ROC 64002 123, University Rd., Sec. 3
  • 2 Jen-Teh Junior College of Medicine, Nursing and Management Department of Occupational Safety and Health Houlong, Miaoli Taiwan, ROC 356 1, Jin-The Rd. Houlong, Miaoli Taiwan, ROC 356 1, Jin-The Rd.
  • 3 National Yunlin University of Science and Technology, NYUST Process Safety and Disaster Prevention Laboratory, Department of Safety, Health, and Environmental Engineering Douliou, Yunlin Taiwan, ROC 64002 123, University Rd., Sec. 3 Douliou, Yunlin Taiwan, ROC 64002 123, University Rd., Sec. 3
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Abstract  

Analytical equations related adiabatic runaway reactions to programmed scanning thermal curves from differential scanning calorimetry (DSC) were proposed. Thermal or pressure hazards can be assessed from the adiabatic trajectories expressed in the analytical equations. These industrially energetic materials include polymerizable monomers, unstable organic peroxides and nitro-compounds. Various emergency relief behaviors, such as tempered vapor, gassy, and hybrid were re-evaluated for calculating vent sizing or mass flow rates from DSC thermal curves and the related physical properties.

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