Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 85: Issue 2
Phase equilibria in the Ag4SSe–As2Se3 system
Authors:
V. Vassilev University of Chemical Technology and Metallurgy Sofia Bulgaria 1756 8 Kliment Ohridski blvd. Sofia Bulgaria 1756 8 Kliment Ohridski blvd.

Search for other papers by V. Vassilev in
Current site
Google Scholar
PubMed Close
,
L. Aljihmani University of Chemical Technology and Metallurgy Sofia Bulgaria 1756 8 Kliment Ohridski blvd. Sofia Bulgaria 1756 8 Kliment Ohridski blvd.

Search for other papers by L. Aljihmani in
Current site
Google Scholar
PubMed Close
, and
V. Parvanova University of Chemical Technology and Metallurgy Sofia Bulgaria 1756 8 Kliment Ohridski blvd. Sofia Bulgaria 1756 8 Kliment Ohridski blvd.

Search for other papers by V. Parvanova in
Current site
Google Scholar
PubMed Close
Pages:
309–314
Online Publication Date:
13 Dec 2005
Publication Date:
01 Aug 2006
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-005-7063-3
Keywords:
Ag4SSe–As2Se3; differential thermal analysis; phase diagram; X-ray diffraction
Restricted access

Abstract  

The phase diagram of the system Ag4SSe–As2Se3 is studied by means of X-ray diffraction, differential thermal analyses and measurements of the microhardness and the density of the materials. The unit-cell parameters of the intermediate phases 3Ag4SSeAs2Se3 (phase A) and Ag4SSe2As2Se3 (phase B) are determined as follows for phase A: a=4.495 , b=3.990 , c=4.042 , α=89.05, β=108.98, γ=92.93; for phase B: a=4.463 , b=4.136 , c=3.752 , α=118.60, β=104.46, γ=83.14. The phase 3Ag4SSeAs2Se3 and Ag4SSe2As2Se3 have a polymorphic transition α↔β consequently at 105 and 120C. The phase A melts incongruently at 390C and phase B congruently at the same temperature.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Apr 2024 14 0 0
May 2024 18 0 0
Jun 2024 4 0 0
Jul 2024 6 0 0
Aug 2024 10 0 0
Sep 2024 21 0 0
Oct 2024 12 0 0