Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 85: Issue 2
Preparation, characterization and thermolysis of metal nitrate complexes with 4,4’-bipyridine
Part 46.
Authors:
G Singh DDU Gorakhpur University Department of Chemistry Gorakhpur India 273009

Search for other papers by G Singh in
Current site
Google Scholar
PubMed Close
,
CP Singh DDU Gorakhpur University Department of Chemistry Gorakhpur India 273009

Search for other papers by CP Singh in
Current site
Google Scholar
PubMed Close
, and
R Frohlich Universitat Münster, 4 Organisch-Chemisches Institut Münster Germany 8149

Search for other papers by R Frohlich in
Current site
Google Scholar
PubMed Close
Pages:
425–431
Online Publication Date:
12 Jan 2006
Publication Date:
01 Aug 2006
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-005-7121-x
Keywords:
isoconversional method; mechanistic pathway; thermal decomposition
Restricted access

Abstract  

Two bis(bipyridine) polymeric metal nitrate complexes with 4,4’-bipyridine of simple formula like [M(bipy)2](NO3)2⋅xH2O (where M=Co, Ni and Cu; x=4, 2 and 0, respectively) have been prepared and characterized. Their thermal decomposition has been undertaken using simultaneous TG-DTG-DTA and DSC in nitrogen atmosphere and non-isothermal TG in air atmosphere. Isothermal TG has been performed at decomposition temperature range of the complexes to evaluate the kinetics of decomposition by applying model-fitting as well as isoconversional method. Possible mechanistic pathways have also been proposed for the thermolysis. Ignition delay measurements have been carried out to investigate the response of these complexes under the condition of rapid heating.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jun 2024 9 0 0
Jul 2024 3 0 0
Aug 2024 12 0 0
Sep 2024 18 1 1
Oct 2024 38 0 0
Nov 2024 41 0 0
Dec 2024 1 0 0