Authors:
H.-L. Liu Central South University College of Chemistry and Chemical Engineering Changsha, Hunan China 410083 Changsha, Hunan China 410083

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S.-J. Liu Central South University College of Chemistry and Chemical Engineering Changsha, Hunan China 410083 Changsha, Hunan China 410083

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Z.-L. Xiao Central South University College of Chemistry and Chemical Engineering Changsha, Hunan China 410083 Changsha, Hunan China 410083

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Q.-Y. Chen Central South University College of Chemistry and Chemical Engineering Changsha, Hunan China 410083 Changsha, Hunan China 410083

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D.-W. Yang Changsha University of Science and Technology Department of Chemistry and Environmental Engineering Changsha, Hunan China 410076 Changsha, Hunan China 410076

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Abstract  

Excess molar enthalpies of binary mixtures for tributyl phosphate (TBP)+methanol/ethanol were measured with a TAM air Isothermal calorimeter at 298.15 K and ambient. The results for xTBP+(1–x)CH3OH are negative in the whole range of composition, while the values for xTBP+(1–x)C2H5OH change from positive values at low x to small negative values at high x. The experimental results have been correlated with the Redlich–Kister polynomial. IR spectra of the mixtures were measured to investigate the effect of hydrogen bonding in the mixture.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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