Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 85: Issue 3
Thermal decomposition kinetic of reactive solids based on isothermal calorimetry measurements
Authors:
X.-R. Li National Research Institute of Fire and Disaster, Tokyo, Japan 181-8633 14-1, Nakahara 3-Chome, Mitaka-shi

Search for other papers by X.-R. Li in
Current site
Google Scholar
PubMed Close
and
H. Koseki National Research Institute of Fire and Disaster, Tokyo, Japan 181-8633 14-1, Nakahara 3-Chome, Mitaka-shi

Search for other papers by H. Koseki in
Current site
Google Scholar
PubMed Close
Pages:
637–642
Online Publication Date:
15 Sep 2006
Publication Date:
01 Sep 2006
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-005-7646-z
Keywords:
decomposition; isothermal method; reaction mechanism; self-accelerating decomposition temperature
Restricted access

Abstract  

An isothermal method was applied to measure the thermal decomposition of reactive solids in a sensitive heat flux reaction calorimeter, C80. This technique experimentally clarified the decomposition mechanisms of unstable substances based on the shapes of the heat flow curves, from which autocatalysis, first-order reaction or pseudo-autocatalytic reaction could be recognized. Kinetic parameters were derived from the measured data.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jun 2024 5 0 0
Jul 2024 7 0 0
Aug 2024 19 0 0
Sep 2024 6 0 0
Oct 2024 32 0 0
Nov 2024 13 0 0
Dec 2024 4 0 0