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  • 1 National Research Institute of Fire and Disaster, Tokyo, Japan 181-8633 14-1, Nakahara 3-Chome, Mitaka-shi
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Abstract  

An isothermal method was applied to measure the thermal decomposition of reactive solids in a sensitive heat flux reaction calorimeter, C80. This technique experimentally clarified the decomposition mechanisms of unstable substances based on the shapes of the heat flow curves, from which autocatalysis, first-order reaction or pseudo-autocatalytic reaction could be recognized. Kinetic parameters were derived from the measured data.