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  • 1 Chinese Academy of Science Thermochemistry Laboratory, Dalian Institute of Chemical Physics Dalian China 116023
  • | 2 Dalian Jiaotong University College of Environmental Science and Engineering Dalian China 116028
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Abstract  

The (R)-BINOL-menthyl dicarbonates, one of the most important compounds in catalytic asymmetric synthesis, was synthesized by a convenient method. The molar heat capacities Cp,m of the compound were measured over the temperature range from 80 to 378 K with a small sample automated adiabatic calorimeter. Thermodynamic functions [HTH298.15] and [STS298.15] were derived in the above temperature range with a temperature interval of 5 K. The thermal stability of the substance was investigated by differential scanning calorimeter (DSC) and a thermogravimetric (TG) technique.

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