Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 87: Issue 2
A kinetic study of the thermal degradation of 3-methylaminopropylamine inside AlPO4-21
Authors:
D. Stojakovic Faculty of Technology and Metallurgy, Belgrade, Serbia and Montenegro, 11000, Karnegijeva 4

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Nevenka Rajic Faculty of Technology and Metallurgy, Belgrade, Serbia and Montenegro, 11000, Karnegijeva 4

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Sanja Sajic Faculty of Technology and Metallurgy, Belgrade, Serbia and Montenegro, 11000, Karnegijeva 4

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Natasa Zabukovec Logar National Institute of Chemistry, Ljubljana, Slovenia, 1000, Hajdrihova 19

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V. Kaucic National Institute of Chemistry, Ljubljana, Slovenia, 1000, Hajdrihova 19

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Pages:
339–343
Online Publication Date:
16 May 2006
Publication Date:
01 Jan 2007
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-005-7382-4
Keywords:
AlPO4-21; kinetic parameters; open-framework; TG; thermal decomposition
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Abstract

Kinetics of the thermal decomposition of 3-methylaminopropylamine which was used as a structure-directing agent in the synthesis of AlPO4-21 has been studied under isothermal and non-isothermal conditions. The decomposition is a single-step reaction occurring in the 573–663 K range. It is a phase-boundary-controlled process, described by the ‘F2/3, R3’ kinetic model. The activation energy values obtained under the non-isothermal and isothermal conditions lie in the 173–151 kJ mol−1 range.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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