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  • 1 Department of Physical Chemistry, Faculty of Chemistry, University of Bucharest, Bvd. Regina Elisabeta Nr. 4-12, Bucharest Romania
  • | 2 Department of Organic Chemistry, Faculty of Chemistry, University of Craiova, Str. Calea Bucuresti, Nr. 107 I, Craiova, Romania
  • | 3 ICPE-CA Advanced Research Institute for Electrical Engineering, Splaiul Unirii 313, Bucharest 74204, Romania
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Abstract

The non-isothermal kinetic parameters corresponding to the decomposition of 4-[(4-chlorobenzyl)oxy]-4′-nitro-azobenzene were evaluated. The kinetic analysis was performed by means of different multi-heating rates methods: isoconversional (‘model-free’) methods (Flynn–Wall–Ozawa) and invariant kinetic parameters method (IKP) associated with the criterion of the independence of activation parameters on the heating rate. The values of the obtained non-isothermal kinetic parameters are in satisfactory agreement.

  • 1 Maciejewski, M Vyazovkin, S 2001 Thermochim. Acta 370 149 .

  • 2 Flynn, JH 1988 J. Thermal Anal. 34 367 .

  • 3 Flynn, JH 1990 J. Thermal Anal. 36 1579 .

  • 4 Malek, J 1992 Thermochim. Acta 200 257 .

  • 5 Vyazovkin, S Wight, CA 1998 Int. Rev. Phys. Chem. 17 407 .

  • 6 Vyazovkin, S Wight, CA 1999 Thermochim. Acta 340/341 53 .

  • 7 Lesnikovich, AI Levchik, SV 1983 J. Thermal Anal. 27 89 .

  • 8 Bourbigot, S Delobel, R Le Bras, M Normand, D 1993 J. Chim. Phys. 90 1909.

  • 9 Budrugeac, P Segal, E Perez-Maqueda, LA Criado, JM 2004 Polym. Degrad. Stab. 84 311 .

  • 10 Radu, S Sarpe-Tudoran, C Jianu, A Rau, G 1998 Rev. Roum. Chim. 43 735.

  • 11 Criado, JM Morales, J 1977 Thermochim. Acta 19 305 .

  • 12 Andonyi, Z Korosi, G 1983 Thermochim. Acta 60 23 .

  • 13 Koga, N Tanaka, H 1991 J. Thermal Anal. 37 347 .

  • 14 Madarász, J Pokol, G Gál, S 1995 J. Thermal Anal. 42 539 .

  • 15 Vyazovkin, S Linert, W 1995 Int. Rev. Phys. Chem. 14 355 .

  • 16 Rose, N Le Bras, M Bourbigot, S Delobel, R 1994 Polym. Degrad. Stab. 45 45 .

  • 17 Campisi, LR Bourbigot, S Le Bras, M Delobel, R 1996 Thermochim. Acta 275 37 .

  • 18 Mortaigne, B Bourbigot, S Le Bras, M Cordellier, G Baundry, A Dufay, J 1999 Polym. Degrad. Stab. 64 443 .

  • 19 Almeras, X Dabrawski, F Le Bras, M Delobel, R Bourbigot, S Marosi, G Anna, P 2002 Polym. Degrad. Stab. 77 315 .

  • 20 Criado, JM Morales, J Brown, ME Maciejewski, M Vyazovkin, S Nomen, R Sempere, J Burnham, AK Opfermann, J Strey, R Anderson, HL Kemmler, A Keuleers, R Janssens, J Desseyn, HO Li, CR Tang, TB Roduit, B Malek, J Mitsuhasni, T 2000 Thermochim. Acta 355 125 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21 Budrugeac, P Segal, E 2001 Int. J. Chem. Kinet. 33 564 .

  • 22 Budrugeac, P 2005 Polym. Degrad. Stab. 89 265 .

  • 23 Roduit, B Borgeat, Ch Berger, B Folly, P Alonso, B Aebischer, JN 2005 J. Therm. Anal. Cal. 79 181 .

  • 24 Budrugeac, P Segal, E 2005 J. Therm. Anal. Cal. 82 677 .

  • 25 Dharwadkar, SR Chandrasekharaiah, MS Karkhanavale, MD 1978 Thermochim. Acta 25 372 .

  • 26 Gotor, FJ Marcias, M Ortega, A Criado, JM 1998 Int. J. Chem. Kinet. 30 647 .

  • 27 Perez-Maqueda, LA Criado, JM Gotor, FJ Malek, J 2002 J. Phys. Chem. 106 2862 .

  • 28 Somasekharan, KN Kalpagam, V 1988 J. Thermal Anal. 34 777 .

  • 29 Dollimore, D et al. 1992 The thermal analysis – techniques and applications Royal Society of Chemistry Cambridge 31 Charsley, R. L., Warrington, S. R. Eds.

    • Search Google Scholar
    • Export Citation
  • 30 Flynn, JH Wall, LA 1966 J. Res. Natl. Bur. Stand. A: Phys. Chem. 70 487.

  • 31 Ozawa, T 1965 Bull. Chem. Soc. Jpn. 38 1881 .

  • 32 Doyle, CD 1962 J. Appl. Polym. Sci. 6 639 .

  • 33 Akahira, T Sunose, T 1971 Res. Report Chiba Inst. Technol. 16 22.

  • 34 Coats, AW Redfern, JP 1964 Nature 201 68 .

  • 35 Budrugeac, P Segal, E 2004 Rev. Roum. Chim. 49 193.

  • 36 Budrugeac, P Criado, JM Gotor, FJ Popescu, C Segal, E 2001 J. Therm. Anal. Cal. 63 777 .

  • 37 Budrugeac, P 2001 Polym. Degrad. Stab. 74 125 .

  • 38 Lesnikovich, VI Ivaskevich, DA Levckik, SV Balabanovich, AI Gaponik, PN Akulak, A 2002 Thermochim. Acta 388 233 .

  • 39 Rajeev, RS De, SK Bhowmick, AK John, B 2003 Polym. Degrad. Stab. 79 449 .

  • 40 Budrugeac, P Criado, JM Gotor, FJ Malek, J Perez-Maqueda, LA Segal, E 2004 Int. J. Chem. Kinet. 36 309 .

  • 41 Mocioiu, O. C., Zaharescu, M., Jitianu, G. and Budrugeac, P., J. Therm. Anal. Cal., OnlineFirst, DOI: 10.1007/s10973-005-7273-8.

  • 42 Radu, S Moanta, A Rau, G Pana, A 2003 Anal. Univ. Craiova 32 77.

  • 43 Šesták, J Berggren, G 1971 Thermochim. Acta 3 1 .

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)