Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 87: Issue 2
Thermodynamic properties of the binary mixture of water and n-butanol
Authors: Z. Nan 1 and Z.-C. Tan 2
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  • 1 Department of Chemistry, Qufu Normal University, Qufu Shandong, P. R. China, 273165
  • | 2 Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, P. R. China, 116023
Pages:
539–544
Online Publication Date:
16 May 2006
Publication Date:
01 Jan 2007
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-005-7295-2
Keywords:
adiabatic calorimetry; heat capacity; low temperature; n-butanol; water
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Abstract

The molar heat capacities of the binary mixture composed of water and n-butanol were measured with an adiabatic calorimeter in the temperature range 78–320 K. The functions of the heat capacity with respect to thermodynamic temperature were established. A glass transition, solid–solid phase transition and solid–liquid phase transition were observed. The corresponding enthalpy and entropy of the solid–liquid phase transition were calculated, respectively. The thermodynamic functions relative to a temperature of 298.15 K were derived based on the relationships of the thermodynamic functions and the function of the measured heat capacity with respect to temperature.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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