Authors: Z. Nan 1 and Z.-C. Tan 2
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  • 1 Department of Chemistry, Qufu Normal University, Qufu Shandong, P. R. China, 273165
  • | 2 Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, P. R. China, 116023
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Abstract

The molar heat capacities of the binary mixture composed of water and n-butanol were measured with an adiabatic calorimeter in the temperature range 78–320 K. The functions of the heat capacity with respect to thermodynamic temperature were established. A glass transition, solid–solid phase transition and solid–liquid phase transition were observed. The corresponding enthalpy and entropy of the solid–liquid phase transition were calculated, respectively. The thermodynamic functions relative to a temperature of 298.15 K were derived based on the relationships of the thermodynamic functions and the function of the measured heat capacity with respect to temperature.

  • 1 Nan, Z Tan, ZC Sun, LX 2004 Acta Phys. Chim. Sin. 20 626.

  • 2 Nan, Z Tan, ZC 2005 J. Chem. Eng. Data 50 6 .

  • 3 Páramo, R Zouine, M Casanova, C 2002 J. Chem. Eng. Data 47 441 .

  • 4 Nan, Z Tan, ZC 2004 J. Therm. Anal. Cal. 76 955 .

  • 5 Wang, SX Tan, ZC Di, YY Xue, F Wang, MH Sun, LX Zhang, T 2004 J. Therm. Anal. Cal. 76 335 .

  • 6 Song, YJ Tan, ZC Lu, SW Xue, Y 2004 J. Therm. Anal. Cal. 77 873 .

  • 7 Xue, P Wang, JY Tan, ZC Lu, SW Meng, SH 2004 J. Therm. Anal. Cal. 76 965 .

  • 8 Liu, BP Tan, ZC Nan, ZD Liu, P Sun, LX Xue, F Lan, XZ 2003 J. Therm. Anal. Cal. 71 623 .

  • 9 Xu, F Sun, LX Tan, ZC Yu, P Zhang, T 2003 J. Therm. Anal. Cal. 74 335 .

  • 10 Sørensen, JM Arlt, W et al. 1979 Chemistry Data Series Dechema Frankfurt, Germany Vol. V, part 1.

  • 11 Tamura, K Hu, J Trandum, C Westh, P Haynes, CA Koga, Y 2000 Phys. Chem. Chem. Phys. 2 355 .

  • 12 Ogawa, H Murakami, S 1986 Thermochim. Acta 109 145 .

  • 13 Archer, DG 1993 J. Phys. Chem. Ref. Data 22 1441 .

  • 14 Parks, GS 1925 J. Am. Chem. Soc. 47 338 .

  • 15 Zorebski, E Chroazewski, M Traczyk, M 2005 J. Chem. Thermodyn. 37 281 .

  • 16 Liu, ZH Hatakeyama, T et al. 2000 Handbook of Analytical Chemistry 2nd Chemical Industry Press Beijing 64.

  • 17 Masson, JF Polomark, GM 2002 Energy Fuels 16 470 .

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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