Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 88: Issue 1
TG-MS characterization of the reaction products of cadmium yellow and malachite artist’s pigments
Authors:
R. White University of Technology Sydney Microstructural Analysis Unit Sydney Australia NSW 2007 PO Box 123 Broadway Sydney Australia NSW 2007 PO Box 123 Broadway

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P. Thomas University of Technology Sydney Dept. Chemistry, Materials and Forensic Science Sydney Australia NSW 2007 PO Box 123 Broadway Sydney Australia NSW 2007 PO Box 123 Broadway

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M. Philips University of Technology Sydney Microstructural Analysis Unit Sydney Australia NSW 2007 PO Box 123 Broadway Sydney Australia NSW 2007 PO Box 123 Broadway

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R. Wuhrer University of Technology Sydney Microstructural Analysis Unit Sydney Australia NSW 2007 PO Box 123 Broadway Sydney Australia NSW 2007 PO Box 123 Broadway

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J. Guerbois University of Technology Sydney Dept. Chemistry, Materials and Forensic Science Sydney Australia NSW 2007 PO Box 123 Broadway Sydney Australia NSW 2007 PO Box 123 Broadway

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Pages:
181–184
Online Publication Date:
08 Apr 2007
Publication Date:
01 Apr 2007
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-006-8134-9
Keywords:
cadmium yellow; malachite; thermogravimetric analysis
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Abstract  

The deleterious interaction of some traditional sulphide artists pigments and copper ions results in the formation of black copper sulphides, in particular, covellite (CuS), and, hence, the discolouration of valuable artworks. In this paper the interaction of malachite, a source of copper(II) ions, with the pigment cadmium yellow, a sulphide pigment comprising of a solid solution of cadmium and zinc sulphides, is investigated by XRD and TG-MS. XRD showed the presence of the copper sulphide and cadmium carbonate phases, produced by a simple ion exchange mechanism. TG-MS showed the complexity of the range of metastable phases produced. The identification of these phases, however, requires further work.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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