Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 88: Issue 3
Kinetic and thermodynamic stability of cluster compounds under heating
Authors:
V. Logvinenko Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

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V. Fedorov Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

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Yu. Mironov Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

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V. Drebushchak Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

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Pages:
687–692
Online Publication Date:
27 Jul 2007
Publication Date:
01 Jun 2007
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-006-8057-5
Keywords:
cluster compounds; compounds stability; dehydration processes; ‘model-free’ kinetics
Restricted access

Abstract  

Dehydration processes of series of rhenium cluster compounds were studied (by thermogravimetry, differential scanning calorimetry, dilatometry methods). Cluster anions of compounds are [Re6S8Br6]3−, [Re6S7Br7]3−, [Re6S8(OH)6]4−, [Re6Se8(OH)6]4−. TG- and DSC-data were used for kinetic studies, these data were processed using special computer program with ‘model-free’ approach. Quantitative data on thermodynamic and kinetic stability of compounds are obtained. The role of water molecules in the cluster compounds stability is discussed.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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