Author: B. Wunderlich
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  • 1 Department of Chemistry, University of Tennessee, Knoxville, TN 37996-1600, USA
  • | 2 Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6197, USA
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This review traces the development of thermal analysis over the last 50 years as it was experienced and contributed to by the author. The article touches upon the beginning of calorimetry and thermal analysis of polymers, the development of differential scanning calorimetry (DSC), single-run DSC, and other special instrumentations, up to the recent addition of modulation to calorimetry and superfast calorimetry. Many new words and phrases have been introduced to the field by the author and his students, leaving a trail of the varied interests over 50 years. It began with cold crystallization and more recently the terms oriented, intermediate phase, glass transitions of crystals, and decoupled chain segments were coined. In-between the following phenomena were named and studied: extended-chain crystals, irreversible thermodynamics of melting of polymer crystals, zero-entropy-production melting, dynamic differential thermal analysis (DDTA), the rule of constant increase of Cp per mobile bead within a molecule at the glass transition temperature, superheating of polymer crystals, melting kinetics, crystallization during polymerization, chin-folding principle, molecular nucleation, rigid amorphous phase, system of classifying molecules, macroconformations, amorphous defects, rules for the entropy of fusion based on molecular shape and flexibility, single-molecule single-crystals, systems for classifying phases and mesophases including condis phases, and the globally metastable semicrystalline polymers with reversible, local subsystems.

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
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Founder Akadémiai Kiadó
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)