This review traces the development of thermal analysis over the last 50 years as it was experienced and contributed to by
the author. The article touches upon the beginning of calorimetry and thermal analysis of polymers, the development of differential
scanning calorimetry (DSC), single-run DSC, and other special instrumentations, up to the recent addition of modulation to
calorimetry and superfast calorimetry.
Many new words and phrases have been introduced to the field by the author and his students, leaving a trail of the varied
interests over 50 years. It began with cold crystallization and more recently the terms oriented, intermediate phase, glass
transitions of crystals, and decoupled chain segments were coined. In-between the following phenomena were named and studied:
extended-chain crystals, irreversible thermodynamics of melting of polymer crystals, zero-entropy-production melting, dynamic
differential thermal analysis (DDTA), the rule of constant increase of Cp per mobile bead within a molecule at the glass transition temperature, superheating of polymer crystals, melting kinetics,
crystallization during polymerization, chin-folding principle, molecular nucleation, rigid amorphous phase, system of classifying
molecules, macroconformations, amorphous defects, rules for the entropy of fusion based on molecular shape and flexibility,
single-molecule single-crystals, systems for classifying phases and mesophases including condis phases, and the globally metastable
semicrystalline polymers with reversible, local subsystems.