Authors:
C. Tonin CNR-ISMAC Institute for Macromolecular Studies Corso G. Pella 16-13900 Biella Italy

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A. Aluigi CNR-ISMAC Institute for Macromolecular Studies Corso G. Pella 16-13900 Biella Italy

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C. Vineis CNR-ISMAC Institute for Macromolecular Studies Corso G. Pella 16-13900 Biella Italy

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A. Varesano CNR-ISMAC Institute for Macromolecular Studies Corso G. Pella 16-13900 Biella Italy

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A. Montarsolo CNR-ISMAC Institute for Macromolecular Studies Corso G. Pella 16-13900 Biella Italy

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F. Ferrero Politecnico di Torino Department of Materials Science and Chemical Engineering Corso Duca degli Abruzzi 24-10129 Torino Italy

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Abstract  

Blends of poly(ethylene oxide) (PEO) and keratin were prepared with the aim of obtaining bio-compatible materials suitable for film and fibre production. Aqueous keratin solutions, prepared by keratin extraction from wool with urea, m-bisulphite and sodium dodecyl sulphates (SDS), filtration and dialysis, were added with different amounts of PEO and solid films were prepared by casting. The addition of SDS prevents protein aggregation. Morphological, thermal and spectroscopic analysis of the films pointed out that keratin hinders the PEO crystallization process, since a progressive decrease in the size of PEO spherulites is observed and the melting point and the related enthalpy decrease with increasing the keratin content. On the other hand, according to thermal and spectroscopic investigations. PEO seems to interfere with the keratin self-assembling giving the protein a different thermal behaviour.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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